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A closed tank has two compartments A and B, both filled with oxygen (assumed to be an ideal gas). The partition separating the two compartments is fixed and is a perfect heat insulator (Figure 1). If the old partition is replaced by a new partition, which can slide and conduct heat does not allow the gas to leak across (Figure 2), the volume (in {{m}^{3}}) of the compartment A after the system attains equilibrium is ______________

Aniket Singh , 1 Month ago
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Askiitians Tutor Team

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To solve this question, let's break it down step by step, considering the properties of the system and the laws of thermodynamics.

### Initial Setup:
- **Compartment A and B** are filled with oxygen, which is assumed to be an ideal gas.
- The partition initially is **fixed** and is a **perfect heat insulator** (Figure 1), meaning no heat exchange occurs between the two compartments.

### Final Setup:
- The old partition is replaced by a **new partition**, which can **slide** and **conduct heat**, but it **does not allow gas to leak** between the compartments (Figure 2).

### Key Assumptions and Principles:
- The gases in compartments A and B are ideal, so we will use the **ideal gas law** PV=nRT, where P is pressure, V is volume, n is the number of moles of gas, R is the universal gas constant, and T is temperature.
- **Thermal equilibrium** is reached, meaning the final temperatures in compartments A and B will be the same.
- The **total volume** of the tank (compartments A and B together) is constant, but the volume distribution between A and B may change due to the sliding partition.
- **No gas leaks**, so the number of moles of gas in each compartment remains the same.

### Step-by-Step Solution:

1. **Initial State**:
In the initial state, the partition is fixed and insulated. The gases in compartments A and B can have different temperatures and pressures.

2. **Final State (Equilibrium)**:
When the partition is replaced by a sliding, heat-conducting partition, the system will evolve to a state of **mechanical equilibrium** and **thermal equilibrium**:
- **Thermal Equilibrium**: The temperature of the gas in compartments A and B must be equal. Let this final temperature be Tf.
- **Mechanical Equilibrium**: The pressure in both compartments must be equal. Let this final pressure be Pf.

3. **Ideal Gas Law for Each Compartment**:
For compartment A, the ideal gas law is:
PfVA=nARTf
For compartment B, the ideal gas law is:
PfVB=nBRTf
Here, nA and nB are the moles of oxygen in compartments A and B, respectively, and VA and VB are the final volumes of compartments A and B.

4. **Volume Conservation**:
The total volume of the system remains constant. If the initial total volume is Vtotal, then:
VA+VB=Vtotal

5. **Mole Conservation**:
The number of moles of gas in each compartment remains the same because no gas leaks across the partition:
- The moles of gas in compartment A is nA.
- The moles of gas in compartment B is nB.

6. **Pressure Equality**:
Since the final pressures are equal, we can equate the ideal gas law equations for compartments A and B:
nAVA=nBVB
This relationship shows that the ratio of moles to volume in each compartment is the same at equilibrium.

7. **Solution**:
Given the conservation of volume and the relationship between moles and volumes, we can solve for the final volume of compartment A VA. However, since specific values for the moles nA and nB or the total volume Vtotal are not provided in the question, the exact numerical value of VA cannot be determined without additional information.

If the total volume and the ratio of moles nA/nB were given, we could use the above equations to find the final volume of compartment A after equilibrium is reached.

### Conclusion:
To find the exact volume of compartment A after equilibrium, more specific numerical information (such as the total volume or the ratio of moles in compartments A and B) is needed. The approach relies on applying the ideal gas law, conservation of volume, and equilibrium conditions for temperature and pressure.

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