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what is the nature of bond in O2 and C2 molecule. explain with the help of MOT

arun gourh , 11 Years ago
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NUKA SIVA KUMAR

Last Activity: 11 Years ago

accoding to molecular orbital theory O2 has paramagntetic nature .VBT and VESPER theory are failed to explain paramagnetic nature of O2.

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Akshay Meena

Last Activity: 11 Years ago

You Already Got The Answer Of O2 .

So, I am just providing you the answer of C2

Carbon Normally Made or it is well known to form Single, Double,Triple C-C bond .

As per VBT   ---  According to the recent theory the carbon forms Quadraple bond (4-bond in between two carbon ) just to satisfy the octet rule for carbon.

Like :

Where Along with 1-Sigma and 2-Pi bond , One weak "inverted" bond is also there as shown in picture which is basically made by the interaction of electrons in two outwardly pointing sp-Hybrd Orbitals.

 

As Per Molecular Orbital Theory (MOT) --- shows that there are two sets of paired electrons in a degenerate pi bonding set of orbitals. This gives a bond order of 2, meaning that there should exist a double bond between the two carbons in a C2 molecule.

 

30_94654_C2.jpg

Thanks & Regards
Akshay Meena, 
askIITians Faculty
M.Tech, IIT Kharagpur

gyan prakash

Last Activity: 11 Years ago

In C2 there are  2∏ bonnds and in O2 there is only one ∏ bond and one sigma bond. U can understand this by

 

c2= σ1S2 σ*1S2 σ2S2 σ*2S2 ∏2px2 ∏py2 it is diamagnetic.

o2=σ1s2  σ*1s2  σ2s2  σ*2s2 ∏2Px2=2py2

it is paramagnetic in nature.

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