Navneet jha
Last Activity: 2 Years ago
Eriochrome Black T is commonly used as indicator for the above titration. At pH 10,
Ca2+(aq) ion first complexes with the indicator as CaIn+(aq) which is wine red. As the
stronger ligand EDTA is added, the CaIn+(aq) complex is replaced by the CaY2-(aq)
complex which is blue. The end point of titration is indicated by a sharp colour change
from wine red to blue.
Titration using Eriochrome Black T as indicator determines total hardness due to Ca2+(aq)
and Mg2+(aq) ions. Hardness due to Ca2+(aq) ion is determined by a separate titration at
a higher pH, by adding NaOH solution to precipitate Mg(OH)2(s), using
hydroxynaphthol blue as indicator.