Ramesh V
Last Activity: 15 Years ago
Starts with the aromatic aldehyde and acid anhydride.Salt of an Carboxylic acid is used to abstract a proton from the alpha carbon of acid anhydride. The carbanion generated would attack the electrophillic centre of aldehyde. This centre is carbonyl carbon. There after an stablised anion is formed. Further hydrolysis gives the required Cinnamic acid.
rn
The Perkin reaction is an organic reaction developed by William Henry Perkin that can be used to make cinnamic acids by the aldol condensation of aromatic aldehydes and acid anhydrides in the presence of an alkali salt of the acid.
rn
rn
You can get the full mechanism preview at :
rn
http://www.springerlink.com/content/h45v0h1782637462/fulltext.pdf?page=1
rn
--
rn
Please feel free to post as many doubts on our disucssion forum as you can. If you find any question difficult to understand - post it here and
rnwe will get you the answer and detailed solution very quickly.We are all IITians and here to help you in your IIT JEE preparation. All the best.
rn
rnRegards,
rnNaga Ramesh
rnIIT Kgp - 2005 batch
rn